Here are some useful links excerpted from "Battery University":
https://batteryuniversity.com/index.php/learn/article/how_to_prolong_lithium_based_batteries
Note:Tables 2, 3 and 4 indicate general aging trends of common cobalt-based Li-ion batteries on depth-of-discharge, temperature and charge levels, Table 6 further looks at capacity loss when operating within given and discharge bandwidths. The tables do not address ultra-fast charging and high load discharges that will shorten battery life. No all batteries behave the same.
Table 2 estimates the number of discharge/charge cycles Li-ion can deliver at various DoD levels before the battery capacity drops to 70 percent. DoD constitutes a full charge followed by a discharge to the indicated state-of-charge (SoC) level in the table.
Depth of discharge
Discharge cycles
(NMC / LiPO4)
Table 2: Cycle life as a function of
depth of discharge.* A partial discharge reduces stress and prolongs battery life, so does a partial charge. Elevated temperature and high currents also affect cycle life.
Note: 100% DoD is a full cycle; 10% is very brief. Cycling in mid-state-of-charge would have best longevity.
100% DoD~300 / 60080% DoD~400 / 90060% DoD~600 / 1,50040% DoD~1,000 / 3,00020% DoD~2,000 / 9,00010% DoD~6,000 / 15,000
Lithium-ion suffers from stress when exposed to heat, so does keeping a cell at a high charge voltage. A battery dwelling above 30°C (86°F) is considered
elevated temperature and for most Li-ion a voltage above 4.10V/cell is deemed as
high voltage. Exposing the battery to high temperature and dwelling in a full state-of-charge for an extended time can be more stressful than cycling. Table 3 demonstrates capacity loss as a function of temperature and SoC.
Temperature
40% charge
100% charge
Table 3: Estimated recoverable capacity when storing Li-ion for one year at various temperatures. Elevated temperature hastens permanent capacity loss. Not all Li-ion systems behave the same.
0°C98% (after 1 year)94% (after 1 year)25°C96% (after 1 year)80% (after 1 year)40°C85% (after 1 year)65% (after 1 year)60°C75% (after 1 year)60%
(after 3 months)
Most Li-ions charge to 4.20V/cell, and every reduction in peak charge voltage of 0.10V/cell is said to double the cycle life. For example, a lithium-ion cell charged to 4.20V/cell typically delivers 300–500 cycles. If charged to only 4.10V/cell, the life can be prolonged to 600–1,000 cycles; 4.0V/cell should deliver 1,200–2,000 and 3.90V/cell should provide 2,400–4,000 cycles.
On the negative side, a lower peak charge voltage reduces the capacity the battery stores. As a simple guideline, every 70mV reduction in charge voltage lowers the overall capacity by 10 percent. Applying the peak charge voltage on a subsequent charge will restore the full capacity.
In terms of longevity, the optimal charge voltage is 3.92V/cell. Battery experts believe that this threshold eliminates all voltage-related stresses; going lower may not gain further benefits but induce other symptoms. (See
BU-808b: What causes Li-ion to die?) Table 4 summarizes the capacity as a function of charge levels. (All values are estimated; Energy Cells with higher voltage thresholds may deviate.)
Charge level (V/cell)
Discharge cycles
Available stored energy
Table 4: Discharge cycles and capacity as a function of charge voltage limit. Every 0.10V drop below 4.20V/cell doubles the cycle but holds less capacity. Raising the voltage above 4.20V/cell would shorten the life. The readings reflect regular Li-ion charging to 4.20V/cell.
Guideline: Every 70mV drop in charge voltage lowers the usable capacity by about 10%.
Note: Partial charging negates the benefit of Li-ion in terms of high specific energy.
[4.30][150–250][110–115%]4.25200–350105–110%
4.20300–500100%4.15400–70090–95%4.10600–1,00085–90%4.05850–1,50080–85%4.001,200–2,00070–75%3.902,400–4,00060–65%3.80See note35–40%3.70See note30% and less
Experiment: Chalmers University of Technology, Sweden, reports that using a reduced charge level of 50% SOC increases the lifetime expectancy of the vehicle Li-ion battery by 44–130%.
Most chargers for mobile phones, laptops, tablets and digital cameras charge Li-ion to 4.20V/cell. This allows maximum capacity, because the consumer wants nothing less than optimal runtime. Industry, on the other hand, is more concerned about longevity and may choose lower voltage thresholds. Satellites and electric vehicles are such examples.
For safety reasons, many lithium-ions cannot exceed 4.20V/cell. (Some NMC are the exception.) While a higher voltage boosts capacity, exceeding the voltage shortens service life and compromises safety. Figure 5 demonstrates cycle count as a function of charge voltage. At 4.35V, the cycle count of a regular Li-ion is cut in half.
Figure 5: Effects on cycle life at elevated charge voltages. Higher charge voltages boost capacity but lowers cycle life and compromises safety.
Source: Choi et al. (2002)
Besides selecting the best-suited voltage thresholds for a given application, a regular Li-ion should not remain at the high-voltage ceiling of 4.20V/cell for an extended time. The Li-ion charger turns off the charge current and the battery voltage reverts to a more natural level. This is like relaxing the muscles after a strenuous exercise. (See
BU-409: Charging Lithium-ion)
Figure 6 illustrates dynamic stress tests (DST) reflecting capacity loss when cycling Li-ion at various charge and discharge bandwidths. The largest capacity loss occurs when discharging a fully charged Li-ion to 25 percent SoC (black); the loss would be higher if fully discharged. Cycling between 85 and 25 percent (green) provides a longer service life than charging to 100 percent and discharging to 50 percent (dark blue). The smallest capacity loss is attained by charging Li-ion to 75 percent and discharging to 65 percent. This, however, does not fully utilize the battery. High voltages and exposure to elevated temperature is said to degrade the battery quicker than cycling under normal condition. (
Nissan Leaf case)
Figure 6: Capacity loss as a function of charge and discharge bandwidth.*
Charging and discharging Li-ion only partially prolongs battery life but reduces utilization.
Case 1: 75–65% SoC offers longest cycle life but delivers only 90,000 energy units (EU). Utilizes 10% of battery.
Case 2: 75–25% SoC has 3,000 cycles (to 90% capacity) and delivers 150,000 EU. Utilizes 50% of battery. (EV battery, new.)
Case 3: 85–25% SoC has 2,000 cycles. Delivers 120,000 EU. Uses 60% of battery.
Case 4: 100–25% SoC; long runtime with 75% use of battery. Has short life. (Mobile phone, drone, etc.)
Courtesy: ResearchGate – Modeling of Lithium-Ion Battery Degradation for Cell Life Assessment.
https://www.researchgate.net/public..._Battery_Degradation_for_Cell_Life_Assessment
* Discrepancies exist between Table 2 and Figure 6 on cycle count. No clear explanations are available other than assuming differences in battery quality and test methods. Variances between low-cost consumer and durable industrial grades may also play a role. Capacity retention will decline more rapidly at elevated temperatures than at 20ºC.
Only a full cycle provides the specified energy of a battery. With a modern
Energy Cell, this is 250Wh/kg, but the cycle life will be compromised. All being linear, the life-prolonging mid-range of 85-25 percent reduces the energy to 60 percent and this equates to moderating the specific energy density from 250Wh/kg to 150Wh/kg. Mobile phones are consumer goods that utilize the full energy of a battery. Industrial devices, such as the EV, typically limit the charge to 85% and discharge to 25% to prolong battery life. (See
Why Mobile Phone Batteries do not last as long as an EV Battery)
Figure 7 extrapolates the data from Figure 6 to expand the predicted cycle life of Li-ion by using an extrapolation program that assumes linear decay of battery capacity with progressive cycling. If this were true, then a Li-ion battery cycled within 75%–25% SoC (blue) would fade to 74% capacity after 14,000 cycles. If this battery were charged to 85% with same depth-of-discharge (green), the capacity would drop to 64% at 14,000 cycles, and with a 100% charge with same DoD (black), the capacity would drop to 48%. For unknown reasons, real-life expectancy tends to be lower than in simulated modeling. (See
BU-208: Cycling Performance)
Figure 7: Predictive modeling of battery life by extrapolation.
Li-ion batteries are charged to three different SoC levels and the cycle life modelled. Limiting the charge range prolongs battery life but decreases energy delivered. This reflects in increased weight and higher initial cost.
With permission to use. Interpolation/extrapolation by OriginLab.
Battery manufacturers often specify the cycle life of a battery with an 80 DoD. This is practical because batteries should retain some reserve before charge under normal use. (See
BU-501: Basics about Discharging, “What Constitutes a Discharge Cycle”) The cycle count on DST (dynamic stress test) differs with battery type, charge time, loading protocol and operating temperature. Lab tests often get numbers that are not attainable in the field.
https://batteryuniversity.com/index.php/learn/article/bu_808b_what_causes_li_ion_to_die