First, the solar production throughout the day looks like a bell curve, so you dont get the full power all day.
Under my conditions, during the longest day of the year a 320W panel that produces 280W at best would produce about 2,200 Wh or the equivalent of almost 8 hours of full production (this is the best possible conditions)
During the shortest day of the year but still under optimal sun condition, that would drop to 1,200 Wh or the equivalent of about 4 hours of full production.
If I look at the full year I get 530,000 Wh for the panel, which averages to 1,450 Wh per day or the equivalent of 5.2 hours of full production daily.
As for your question regarding a multi-source charger prioritizing the solar input over the AC input, it is definitely possible but depends entirely on the Multi charger you are using.
I believe the Victron Multiplus can be configured to do that.