Short answer: both ebike and 12V battery will be charging from solar at the same time.
Long answer:
Yes, it would take all day to charge 12V lead acid battery from 50% to 99% because charging slows down once it's charged to 80-85%.
But your ebike battery could get fully charged because ebike battery will be stealing solar power from 12V battery. Solar will be charging 12V battery
and running inverter at the same time - if there is enough charge in 12V battery, otherwise voltage under load will drop below 11 and inverter will shut down.
Solar panels are 80-90% efficient, summer day should be counted as 5 hours of "full sun", 100W solar will generate 400-450 WH a day. That is - on a good day, no heavy clouds.
As long as the 12V battery remains above 50% (to support the load) and your ebike charger is reasonable 100-140W, not 300W, you should be fine. You will need at least 90-100 AH 12V battery, and it has to be FULL at the beginning, because 150W ebike charger will drain 12V battery faster than 100W solar will generate, and the "deficit" will be taken out of 12V battery. Or get 200W solar, but at this point solar array becomes uncomfortably large for a portable setup.
Edit-PS: for easy solar check Renogy solar suitcase
https://www.renogy.com/renogy-100-watt-12-volt-monocrystalline-foldable-solar-suitcase-w-voyager/. 100W solar folds in half like a folding table, solar charger is bolted under the panel. Run a pair of cables with crocodiles to 12V battery, - done. I would not buy this for myself because $3 per watt is too expensive today, you can install 2-3 times bigger array on your van for that price, if you are handy. But, if you are not, "suitcase" is the easy way in.
Inexpensive 300W Pure Sine inverter - (there could be cheaper, but Samlex is a decent quality for the price):
https://www.amazon.com/Samlex-Solar-PST-300-12-Pure-Inverter/dp/B00H8N97E2