hey, sure thing, i feel you. To get the perfect alignment, first step is to make it work somehow (you did that)
Put the bike on the repair stand, shift into the middle gear, 5 or 6 sprocket, pedal with one hand and slowly make micro adjustments in one direction until the derailleur shifts into the next gear (wrong gear) and count the clicks it took from your original position. lets say from your original position it took 20 clicks until the gear jumped into the wrong gear. (That is the limit on one side.) now micro adjust exactly the same amout of clicks (20) to shift back to where you started. Repeat in the other direction. now lets say it took you 16 clicks until it shifted a gear again. that means you are not exactly in the center of your 2 gears. you need to micro shift 2 times in the direction you had 20 clicks from your original position. (that way when you repeat the process, it will take you 18 mircroshifts to misshift up and 18 to misshift down. that way you know you are EXACTLY in the center.
Make sure your B-scew is set correctly. after you did that it should shift crisp af, if there is problems in your lowest 2 gears its the lower limit screw, and with the highers gear, its the upper limit screw.
The only way to find the center is to find the point where it shifts up and down. Nobody is perfect by eye. It is hard to explain but the principle is simple. With normal derailleurs you would use quarter turns to find that point.
I will make a youtube video one day to explain the shifting, not much good stuff out there. Most just tell you to look down the derailleur and set it centered. I have a good eye, and it looks all good to me. This method is the best out there.